Dark Mode Light Mode
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.

Probing far-from-equilibrium dynamics of electrical double layers

Probing far-from-equilibrium dynamics of electrical double layers Probing far-from-equilibrium dynamics of electrical double layers


  • Gonella, G. et al. Water at charged interfaces. Nat. Rev. Chem. 5, 466–485 (2021).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Strmcnik, D. et al. The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum. Nat. Chem. 1, 466–472 (2009).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Park, S., Shao, Y. Y., Liu, J. & Wang, Y. Oxygen electrocatalysts for water electrolyzers and reversible fuel cells: status and perspective. Energy Environ. Sci. 5, 9331–9344 (2012).

    Article 
    CAS 

    Google Scholar
     

  • Lopes, P. P. et al. Double layer effects in electrocatalysis: the oxygen reduction reaction and ethanol oxidation reaction on Au(111), Pt(111) and Ir(111) in alkaline media containing Na and Li cations. Catal. Today 262, 41–47 (2016).

    Article 
    CAS 

    Google Scholar
     

  • Frumkin, A. N., Nikolaeva-Fedorovich, N. V., Berezina, N. P. & Keis, K. E. The electroreduction of the S2O82− anion. J. Electroanal. Chem. Interfacial Electrochem. 58, 189–201 (1975).

    Article 
    CAS 

    Google Scholar
     

  • Resasco, J. et al. Promoter effects of alkali metal cations on the electrochemical reduction of carbon dioxide. J. Am. Chem. Soc. 139, 11277–11287 (2017).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Ringe, S. et al. Understanding cation effects in electrochemical CO2 reduction. Energy Environ. Sci. 12, 3001–3014 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Ludwig, T. et al. Atomistic insight into cation effects on binding energies in Cu-catalyzed carbon dioxide reduction. J. Phys. Chem. C 124, 24765–24775 (2020).

    Article 
    CAS 

    Google Scholar
     

  • Monteiro, M. C. O. et al. Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution. Nat. Catal. 4, 654–662 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Gouy, M. Sur la constitution de la charge électrique à la surface d’un électrolyte. J. Phys. Theor. Appl. 9, 457–468 (1910).

    Article 
    CAS 

    Google Scholar
     

  • Chapman, D. L. A contribution to the theory of electrocapillarity. Lond. Edinb. Dublin Philos. Mag. J. Sci. 25, 475–481 (1913).

    Article 

    Google Scholar
     

  • Stern, O. Zur theorie der elektrolytischen doppelschicht. Z. Elektrochem. Angew. Phys. Chem. 30, 508–516 (1924).

    CAS 

    Google Scholar
     

  • Grahame, D. C. The electrical double layer and the theory of electrocapillarity. Chem. Rev. 41, 441–501 (1947).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Devanathan, M. A. V. & Tilak, B. V. K. S. R. A. The structure of the electrical double layer at the metal-solution interface. Chem. Rev. 65, 635–684 (1965).

    Article 
    CAS 

    Google Scholar
     

  • Parsons, R. Electrical double-layer: recent experimental and theoretical developments. Chem. Rev. 90, 813–826 (1990).

    Article 
    CAS 

    Google Scholar
     

  • Zhang, L.-L., Li, C.-K. & Huang, J. A beginners’ guide to modelling of electric double layer under equilibrium, nonequilibrium and AC conditions. J. Electrochem. 28, 2108471 (2022).


    Google Scholar
     

  • Conway, B. E. Individual solvated ion properties and specificity of ion adsorption effects in processes at electrodes. Chem. Soc. Rev. 21, 253–261 (1992).

    Article 
    CAS 

    Google Scholar
     

  • Ayranci, E. & Conway, B. E. Size, shape and charge effects in the partial molal volume, compressibility and electrostriction behaviour of sulphur and chlorine oxyanions in water. J. Chem. Soc. Faraday Trans. 79, 1357–1372 (1983).

    Article 
    CAS 

    Google Scholar
     

  • Marcus, Y. Electrostriction in electrolyte solutions. Chem. Rev. 111, 2761–2783 (2011).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Huang, B. et al. Cation- and pH-dependent hydrogen evolution and oxidation reaction kinetics. JACS Au 1, 1674–1687 (2021).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Gu, J. et al. Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium. Nat. Catal. 5, 268–276 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Li, X.-Y. et al. Mechanism of cations suppressing proton diffusion kinetics for electrocatalysis. Angew. Chem. Int. Ed. 62, e202218669 (2023).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Yao, Y., Delmo, E. P. & Shao, M. The electrode/electrolyte interface study during the electrochemical CO2 reduction in acidic electrolytes. Angew. Chem. Int. Ed. 64, e202415894 (2024).

    Article 

    Google Scholar
     

  • Zhang, Z. et al. Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media. Nat. Catal. 7, 807–817 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Thaemer, M., De Marco, L., Ramasesha, K., Mandal, A. & Tokmakoff, A. Ultrafast 2D IR spectroscopy of the excess proton in liquid water. Science 350, 78–82 (2015).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Zhu, B. et al. Proton accumulation near the Au electrode/acid interface probed by electrochemical in situ infrared spectroscopy. J. Phys. Chem. C 129, 11958–11966 (2025).

    Article 
    CAS 

    Google Scholar
     

  • Zhang, Z. et al. Molecular understanding of the critical role of alkali metal cations in initiating CO2 electroreduction on Cu(100) surface. Nat. Commun. 15, 612 (2024).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Scatena, L. F., Brown, M. G. & Richmond, G. L. Water at hydrophobic surfaces: weak hydrogen bonding and strong orientation effects. Science 292, 908–912 (2001).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Osawa, M., Tsushima, M., Mogami, H., Samjeské, G. & Yamakata, A. Structure of water at the electrified platinum–water interface: a study by surface-enhanced infrared absorption spectroscopy. J. Phys. Chem. C 112, 4248–4256 (2008).

    Article 
    CAS 

    Google Scholar
     

  • Wang, Y. H. et al. In situ Raman spectroscopy reveals the structure and dissociation of interfacial water. Nature 600, 81–85 (2021).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Chen, J. & Wang, T. DPχ: a charge-based machine learning potential validated on the Pt(111)-water electrochemical interface. J. Chem. Theory Comput. 22, 8493–8501 (2026).

  • Li, C. et al. In situ probing electrified interfacial water structures at atomically flat surfaces. Nat. Mater. 18, 697–701 (2019).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Meng, S., Xu, L., Wang, E. & Gao, S. Vibrational recognition of hydrogen-bonded water networks on a metal surface. Phys. Rev. Lett. 89, 176104 (2002).

    Article 
    ADS 
    PubMed 

    Google Scholar
     

  • Yamakata, A., Soeta, E., Ishiyama, T., Osawa, M. & Morita, A. Real-time observation of the destruction of hydration shells under electrochemical force. J. Am. Chem. Soc. 135, 15033–15039 (2013).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Kresse, G. & Furthmuller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15–50 (1996).

    Article 
    CAS 

    Google Scholar
     

  • Kresse, G. & Furthmuller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169–11186 (1996).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Hammer, B., Hansen, L. B. & Norskov, J. K. Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals. Phys. Rev. B 59, 7413–7421 (1999).

    Article 
    ADS 

    Google Scholar
     

  • Blochl, P. E. Projector augmented-wave method. Phys. Rev. B 50, 17953–17979 (1994).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Kresse, G. & Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59, 1758–1775 (1999).

    Article 
    ADS 
    CAS 

    Google Scholar
     



  • Source link

    Keep Up to Date with the Most Important News

    By pressing the Subscribe button, you confirm that you have read and are agreeing to our Privacy Policy and Terms of Use
    Add a comment Add a comment

    Leave a Reply

    Your email address will not be published. Required fields are marked *

    Previous Post
    The nutritional value of invertebrate aquatic foods

    The nutritional value of invertebrate aquatic foods

    Next Post
    Designing physics experiments with artificial intelligence

    Designing physics experiments with artificial intelligence

    Advertisement