Dark Mode Light Mode

Keep Up to Date with the Most Important News

By pressing the Subscribe button, you confirm that you have read and are agreeing to our Privacy Policy and Terms of Use
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.

Dendrite initiation and deflection in biaxially stressed solid electrolytes

Dendrite initiation and deflection in biaxially stressed solid electrolytes Dendrite initiation and deflection in biaxially stressed solid electrolytes


  • Janek, J. & Zeier, W. G. A solid future for battery development. Nat. Energy 1, 16141 (2016).

    Article 
    ADS 

    Google Scholar
     

  • Janek, J. & Zeier, W. G. Challenges in speeding up solid-state battery development. Nat. Energy 8, 230–240 (2023).

    Article 
    ADS 

    Google Scholar
     

  • Albertus, P., Babinec, S., Litzelman, S. & Newman, A. Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries. Nat. Energy 3, 16–21 (2018).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Cheng, E. J., Sharafi, A. & Sakamoto, J. Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte. Electrochim. Acta 223, 85–91 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Kazyak, E. et al. Li penetration in ceramic solid electrolytes: operando microscopy analysis of morphology, propagation, and reversibility. Matter 2, 1025–1048 (2020).

    Article 

    Google Scholar
     

  • Han, F. et al. High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes. Nat. Energy 4, 187–196 (2019).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Liu, H. et al. Dendrite formation in solid-state batteries arising from lithium plating and electrolyte reduction. Nat. Mater. 24, 581–588 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Tian, H.-K., Xu, B. & Qi, Y. Computational study of lithium nucleation tendency in Li7La3Zr2O12 (LLZO) and rational design of interlayer materials to prevent lithium dendrites. J. Power Sources 392, 79–86 (2018).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Tian, H.-K., Liu, Z., Ji, Y., Chen, L.-Q. & Qi, Y. Interfacial electronic properties dictate Li dendrite growth in solid electrolytes. Chem. Mater. 31, 7351–7359 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Porz, L. et al. Mechanism of lithium metal penetration through inorganic solid electrolytes. Adv. Energy Mater. 7, 1701003 (2017).

    Article 

    Google Scholar
     

  • Gao, H. et al. Visualizing the failure of solid electrolyte under GPa-level interface stress induced by lithium eruption. Nat. Commun. 13, 5050 (2022).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Swamy, T. et al. Lithium Metal penetration induced by electrodeposition through solid electrolytes: example in single-crystal Li6La3ZrTaO12 garnet. J. Electrochem. Soc. 165, A3648–A3655 (2018).

    Article 
    CAS 

    Google Scholar
     

  • McConohy, G. et al. Mechanical regulation of lithium intrusion probability in garnet solid electrolytes. Nat. Energy 8, 241–250 (2023).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Zhang, Y. et al. Mechanically driven Li dendrite penetration in garnet solid electrolyte. Nature 652, 912–918 (2026).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Athanasiou, C. E. et al. Operando measurements of dendrite-induced stresses in ceramic electrolytes using photoelasticity. Matter 7, 95–106 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Ning, Z. et al. Dendrite initiation and propagation in lithium metal solid-state batteries. Nature 618, 287–293 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, B. et al. Atomic mechanism of lithium dendrite penetration in solid electrolytes. Nat. Commun. 16, 1906 (2025).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Xue, D. et al. Dynamic interplay of dendrite growth and cracking in lithium metal solid-state batteries. J. Mech. Phys. Solids 202, 106197 (2025).

    Article 
    CAS 

    Google Scholar
     

  • Kalnaus, S., Dudney, N. J., Westover, A. S., Herbert, E. & Hackney, S. Solid-state batteries: the critical role of mechanics. Science 381, eabg5998 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Sandoval, S. E. et al. Electro-chemo-mechanics of anode-free solid-state batteries. Nat. Mater. 24, 673–681 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Flatscher, F. et al. Deflecting dendrites by introducing compressive stress in Li7La3Zr2O12 using ion implantation. Small 20, 2307515 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Thomas, C. et al. Stress engineering for crack and dendrite prevention in solid electrolytes via ion implantation. Cell Rep. Phys. Sci. 6, 102544 (2025).

  • Xu, X. et al. Heterogeneous doping via nanoscale coating impacts the mechanics of Li intrusion in brittle solid electrolytes. Nat. Mater. 25, 627–634 (2026).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yu, Z. et al. Dendrite suppression in garnet electrolytes via thermally induced compressive stress. Joule 10, 102232 (2026).

    Article 
    CAS 

    Google Scholar
     

  • Liu, X. et al. Local electronic structure variation resulting in Li ‘filament’ formation within solid electrolytes. Nat. Mater. 20, 1485–1490 (2021).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhu, C. et al. Understanding the evolution of lithium dendrites at Li6.25Al0.25La3Zr2O12 grain boundaries via operando microscopy techniques. Nat. Commun. 14, 1300 (2023).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Fincher, C. D. et al. Controlling dendrite propagation in solid-state batteries with engineered stress. Joule 6, 2794–2809 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Anderson, T. L. Fracture Mechanics—Fundamentals and Applications (Taylor & Francis, 2017).

  • Cook, R. F. & DelRio, F. W. Determination of ceramic flaw populations from component strengths. J. Am. Ceram. Soc. 102, 4794–4808 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Yang, L., Gao, Y., Chen, Y. & Ding, B. Mechanisms of transverse bowl-shaped crack in all solid-state batteries. Eng. Fract. Mech. 321, 111117 (2025).

    Article 

    Google Scholar
     

  • Siniscalchi, M. et al. Initiation of dendritic failure of LLZTO via sub-surface lithium deposition. Energy Environ. Sci. 17, 2431–2440 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Fuchs, T., Haslam, C. G., Richter, F. H., Sakamoto, J. & Janek, J. Evaluating the use of critical current density tests of symmetric lithium transference cells with solid electrolytes. Adv. Energy Mater. 13, 2302383 (2023).

    Article 
    CAS 

    Google Scholar
     

  • Klimpel, M., Zhang, H., Kovalenko, M. V. & Kravchyk, K. V. Standardizing critical current density measurements in lithium garnets. Commun. Chem. 6, 192 (2023).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Famprikis, T., Canepa, P., Dawson, J. A., Islam, M. S. & Masquelier, C. Fundamentals of inorganic solid-state electrolytes for batteries. Nat. Mater. 18, 1278–1291 (2019).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Bardeen, J. Electrical conductivity of metals. J. Appl. Phys. 11, 88–111 (1940).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Counihan, M. J. et al. The phantom menace of dynamic soft-shorts in solid-state battery research. Joule 8, 64–90 (2023).

    Article 

    Google Scholar
     

  • Wang, C. et al. Identifying soft breakdown in all-solid-state lithium battery. Joule 6, 1770–1781 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Guo, W. et al. In-situ optical observation of Li growth in garnet-type solid state electrolyte. Energy Storage Mater. 41, 791–797 (2021).

    Article 
    ADS 

    Google Scholar
     

  • Yu, S. & Siegel, D. J. Grain boundary contributions to Li-ion transport in the solid electrolyte Li7La3Zr2O12 (LLZO). Chem. Mater. 29, 9639–9647 (2017).

    Article 
    CAS 

    Google Scholar
     

  • Yu, S. & Siegel, D. J. Grain boundary softening: a potential mechanism for lithium metal penetration through stiff solid electrolytes. ACS Appl. Mater. Interfaces 10, 38151–38158 (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yildirim, C. et al. Understanding the origin of lithium dendrite branching in Li6.5La3Zr1.5Ta0.5O12 solid-state electrolyte via microscopy measurements. Nat. Commun. 15, 8207 (2024).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Xie, X. et al. Lithium expulsion from the solid-state electrolyte Li6.4La3Zr1.4Ta0.6O12 by controlled electron injection in a SEM. ACS Appl. Mater. Interfaces 10, 5978–5983 (2018).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Krauskopf, T. et al. Lithium-metal growth kinetics on LLZO garnet-type solid electrolytes. Joule 3, 2030–2049 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Wang, S. et al. Effect of H+ exchange and surface impurities on bulk and interfacial electrochemistry of garnet solid electrolytes. Chem. Mater. 36, 6849–6864 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Krauskopf, T., Richter, F. H., Zeier, W. G. & Janek, J. Physicochemical concepts of the lithium metal anode in solid-state batteries. Chem. Rev. 120, 7745–7794 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wang, T. et al. Fatigue of Li metal anode in solid-state batteries. Science 388, 311–316 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Dixit, M. B. et al. Polymorphism of garnet solid electrolytes and its implications for grain-level chemo-mechanics. Nat. Mater. 21, 1298–1305 (2022).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Luo, Q. & Jones, A. H. High-precision determination of residual stress of polycrystalline coatings using optimised XRD-sin2ψ technique. Surf. Coat. Technol. 205, 1403–1408 (2010).

    Article 
    CAS 

    Google Scholar
     

  • Yu, S. et al. Elastic properties of the solid electrolyte Li7La3Zr2O12 (LLZO). Chem. Mater. 28, 197–206 (2016).

    Article 
    CAS 

    Google Scholar
     

  • Newville, M. et al. LMFIT: non-linear least-squares minimization and curve-fitting for Python. Zenodo https://doi.org/10.5281/zenodo.15014437 (2025).

  • Santhosha, A. L., Medenbach, L., Buchheim, J. R. & Adelhelm, P. The indium−lithium electrode in solid-state lithium-ion batteries: phase formation, redox potentials, and interface stability. Batter. Supercaps 2, 524–529 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Coelho, A. A. TOPAS and TOPAS-Academic: an optimization program integrating computer algebra and crystallographic objects written in C++. J. Appl. Crystallogr. 51, 210–218 (2018).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Kataoka, K. & Akimoto, J. Lithium-ion conductivity and crystal structure of garnet-type solid electrolyte Li7xLa3Zr2−xTaxO12 using single-crystal. J. Ceram. Soc. Jpn 127, 521–526 (2019).

    Article 
    CAS 

    Google Scholar
     

  • Fairley, N. et al. Systematic and collaborative approach to problem solving using X-ray photoelectron spectroscopy. Appl. Surf. Sci. Adv. 5, 100112 (2021).

    Article 

    Google Scholar
     

  • Bunger, A. P. & Detournay, E. Asymptotic solution for a penny-shaped near-surface hydraulic fracture. Eng. Fract. Mech. 72, 2468–2486 (2005).

    Article 
    ADS 

    Google Scholar
     

  • Zhang, X., Detournay, E. & Jeffrey, R. Propagation of a penny-shaped hydraulic fracture parallel to the free-surface of an elastic half-space. Int. J. Fract. 115, 125–158 (2002).

    Article 
    ADS 

    Google Scholar
     

  • Cui, T., Lee, S. & Wang, S. Dendrite initiation and deflection in biaxially stressed solid electrolytes. Zenodo https://doi.org/10.5281/zenodo.20373114 (2026).



  • Source link

    Keep Up to Date with the Most Important News

    By pressing the Subscribe button, you confirm that you have read and are agreeing to our Privacy Policy and Terms of Use
    Add a comment Add a comment

    Leave a Reply

    Your email address will not be published. Required fields are marked *

    Previous Post
    Hadean bridgmanite in the source of a present-day ocean island

    Hadean bridgmanite in the source of a present-day ocean island

    Next Post
    Steatosis shapes prognosis-defining liver metastasis heterogeneity in CRC

    Steatosis shapes prognosis-defining liver metastasis heterogeneity in CRC

    Advertisement