Dark Mode Light Mode
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.
Join us on a journey where chemistry meets creativity, and the wonders of science unfold. Quench your intellectual thirst with thought-provoking articles that transcend the boundaries of conventional knowledge.

Scalable quasi-pure MOF membranes for energy-efficient gas separations

Scalable quasi-pure MOF membranes for energy-efficient gas separations Scalable quasi-pure MOF membranes for energy-efficient gas separations


  • Sholl, D. S. & Lively, R. P. Seven chemical separations to change the world. Nature 532, 435–437 (2016).

    Article 
    ADS 
    PubMed 

    Google Scholar
     

  • Zhou, S. et al. Asymmetric pore windows in MOF membranes for natural gas valorization. Nature 606, 706–712 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Qian, Q. et al. MOF-based membranes for gas separations. Chem. Rev. 120, 8161–8266 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Jiang, H., Alezi, D. & Eddaoudi, M. A reticular chemistry guide for the design of periodic solids. Nat. Rev. Mater. 6, 466–487 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Lin, R.-B. et al. Molecular sieving of ethylene from ethane using a rigid metal–organic framework. Nat. Mater. 17, 1128–1133 (2018).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Knebel, A. & Caro, J. Metal–organic frameworks and covalent organic frameworks as disruptive membrane materials for energy-efficient gas separation. Nat. Nanotechnol. 17, 911–923 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhou, S. et al. Electrochemical synthesis of continuous metal–organic framework membranes for separation of hydrocarbons. Nat. Energy 6, 882–891 (2021).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Knebel, A. et al. Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids. Nat. Mater. 19, 1346–1353 (2020).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Cadiau, A., Adil, K., Bhatt, P. M., Belmabkhout, Y. & Eddaoudi, M. A metal-organic framework–based splitter for separating propylene from propane. Science 353, 137–140 (2016).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Lai, H. W. H. et al. Hydrocarbon ladder polymers with ultrahigh permselectivity for membrane gas separations. Science 375, 1390–1392 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Luo, X. et al. Wrinkled metal-organic framework thin films with tunable Turing patterns for pliable integration. Science 385, 647–651 (2024).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Peng, Y. et al. Metal-organic framework nanosheets as building blocks for molecular sieving membranes. Science 346, 1356–1359 (2014).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Xu, L.-H. et al. Highly flexible and superhydrophobic MOF nanosheet membrane for ultrafast alcohol-water separation. Science 378, 308–313 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Ma, X. et al. Zeolitic imidazolate framework membranes made by ligand-induced permselectivation. Science 361, 1008–1011 (2018).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhou, S. et al. Paralyzed membrane: current-driven synthesis of a metal-organic framework with sharpened propene/propane separation. Sci. Adv. 4, eaau1393 (2018).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Hou, Q., Zhou, S., Wei, Y., Caro, J. & Wang, H. Balancing the grain boundary structure and the framework flexibility through bimetallic metal–organic framework (MOF) membranes for gas separation. J. Am. Chem. Soc. 142, 9582–9586 (2020).

    CAS 
    PubMed 

    Google Scholar
     

  • Zhao, Y. et al. Flexible polypropylene-supported ZIF-8 membranes for highly efficient propene/propane separation. J. Am. Chem. Soc. 142, 20915–20919 (2020).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Liang, Y. et al. Large-area ultrathin metal–organic framework membranes fabricated on flexible polymer supports for gas separations. Angew. Chem. Int. Ed. 63, e202404058 (2024).

    Article 
    CAS 

    Google Scholar
     

  • Ma, Q. et al. Ultrafast semi-solid processing of highly durable ZIF-8 membranes for propylene/propane separation. Angew. Chem. Int. Ed. 132, 22093–22098 (2020).

    Article 

    Google Scholar
     

  • Shu, L., Peng, Y., Zhu, C., Li, K. & Yang, W. Metal-organic framework membranes with scale-like structure for efficient propylene/propane separation. Nat. Commun. 15, 10437 (2024).

    Article 
    ADS 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Dakhchoune, M. et al. Gas-sieving zeolitic membranes fabricated by condensation of precursor nanosheets. Nat. Mater. 20, 362–369 (2021).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Chen, G. et al. Solid-solvent processing of ultrathin, highly loaded mixed-matrix membrane for gas separation. Science 381, 1350–1356 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Datta, S. J. et al. Rational design of mixed-matrix metal-organic framework membranes for molecular separations. Science 376, 1080–1087 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Tan, X. et al. Truly combining the advantages of polymeric and zeolite membranes for gas separations. Science 378, 1189–1194 (2022).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Koros, W. J. & Zhang, C. Materials for next-generation molecularly selective synthetic membranes. Nat. Mater. 16, 289–297 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Napper, D. H. Polymeric Stabilization of Colloidal Dispersions (Academic Press, 1983).

  • de Gennes, P. G. Polymers at an interface; a simplified view. Adv. Colloid Interface Sci. 27, 189–209 (1987).

    Article 

    Google Scholar
     

  • Lin, J.-B. et al. A scalable metal-organic framework as a durable physisorbent for carbon dioxide capture. Science 374, 1464–1469 (2021).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Rodenas, T. et al. Metal–organic framework nanosheets in polymer composite materials for gas separation. Nat. Mater. 14, 48–55 (2015).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Wei, R. et al. Carbon nanotube supported oriented metal organic framework membrane for effective ethylene/ethane separation. Sci. Adv. 8, eabm6741 (2022).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Li, G., Zhang, H. & Han, Y. Applications of transmission electron microscopy in phase engineering of nanomaterials. Chem. Rev. 123, 10728–10749 (2023).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, D. et al. Atomic-resolution transmission electron microscopy of electron beam–sensitive crystalline materials. Science 359, 675–679 (2018).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhang, H. et al. Three-dimensional inhomogeneity of zeolite structure and composition revealed by electron ptychography. Science 380, 633–638 (2023).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Zhu, Y. et al. Unravelling surface and interfacial structures of a metal–organic framework by transmission electron microscopy. Nat. Mater. 16, 532–536 (2017).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Ozcan, A. et al. Tuning MOF/polymer interfacial pore geometry in mixed matrix membrane for upgrading CO2 separation performance. Sci. Adv. 10, eadk5846 (2024).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Wegst, U. G. K., Bai, H., Saiz, E., Tomsia, A. P. & Ritchie, R. O. Bioinspired structural materials. Nat. Mater. 14, 23–36 (2015).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Batatia, I. et al. A foundation model for atomistic materials chemistry. J. Chem. Phys. 163, 184110 (2025).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Hjorth Larsen, A. et al. The atomic simulation environment—a Python library for working with atoms. J. Phys. Condens. Matter 29, 273002 (2017).

    Article 
    PubMed 

    Google Scholar
     

  • Hafner, J. Ab-initio simulations of materials using VASP: density-functional theory and beyond. J. Comput. Chem. 29, 2044–2078 (2008).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Grimme, S. Density functional theory with London dispersion corrections. Wiley Interdiscip. Rev. Comput. Mol. Sci. 1, 211–228 (2011).

    Article 
    CAS 

    Google Scholar
     

  • Dudarev, S. L., Botton, G. A., Savrasov, S. Y., Humphreys, C. J. & Sutton, A. P. Electron-energy-loss spectra and the structural stability of nickel oxide: an LSDA+U study. Phys. Rev. B 57, 1505–1509 (1998).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Limas, N. G. & Manz, T. A. Introducing DDEC6 atomic population analysis: part 2. Computed results for a wide range of periodic and nonperiodic materials. RSC Adv. 6, 45727–45747 (2016).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Rappé, A. K., Casewit, C. J., Colwell, K. S., Goddard, W. A. III & Skiff, W. M. UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations. J. Am. Chem. Soc. 114, 10024–10035 (1992).

    Article 
    ADS 

    Google Scholar
     

  • Boyd, P. G., Moosavi, S. M., Witman, M. & Smit, B. Force-field prediction of materials properties in metal-organic frameworks. J. Phys. Chem. Lett. 8, 357–363 (2017).

    Article 
    CAS 
    PubMed 
    PubMed Central 

    Google Scholar
     

  • Thompson, A. P. et al. LAMMPS – a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales. Comput. Phys. Commun. 271, 108171 (2022).

    Article 
    CAS 

    Google Scholar
     

  • Abbott, L. J., Hart, K. E. & Colina, C. M. Polymatic: a generalized simulated polymerization algorithm for amorphous polymers. Theor. Chem. Acc. 132, 1334 (2013).

    Article 

    Google Scholar
     

  • Wang, J., Wolf, R. M., Caldwell, J. W., Kollman, P. A. & Case, D. A. Development and testing of a general amber force field. J. Comput. Chem. 25, 1157–1174 (2004).

    Article 
    ADS 
    CAS 
    PubMed 

    Google Scholar
     

  • Semino, R., Ramsahye, N. A., Ghoufi, A. & Maurin, G. Microscopic model of the metal–organic framework/polymer interface: a first step toward understanding the compatibility in mixed matrix membranes. ACS Appl. Mater. Interfaces 8, 809–819 (2016).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Fan, D. et al. Is porosity at the MOF/polymer interface necessarily an obstacle to optimal gas-separation performances in mixed matrix membranes? ACS Mater. Lett. 3, 344–350 (2021).

    Article 
    CAS 

    Google Scholar
     

  • Diaz-Marquez, A., Naskar, S., Fan, D., Eddaoudi, M. & Maurin, G. MOF surface morphology governs interfacial pore architecture and CO2 dynamics in mixed matrix membranes. Chem. Sci. 16, 19519–19531 (2025).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Yang, Q. & Zhong, C. Molecular simulation of carbon dioxide/methane/hydrogen mixture adsorption in metal−organic frameworks. J. Phys. Chem. B. 110, 17776–17783 (2006).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Martin, M. G. & Siepmann, J. I. Transferable potentials for phase equilibria. 1. United-atom description of n-alkanes. J. Phys. Chem. B 102, 2569–2577 (1998).

    Article 
    CAS 

    Google Scholar
     

  • Wells, B. A. & Chaffee, A. L. Ewald summation for molecular simulations. J. Chem. Theory Comput. 11, 3684–3695 (2015).

    Article 
    CAS 
    PubMed 

    Google Scholar
     

  • Peng, D.-Y. & Robinson, D. B. A new two-constant equation of state. Ind. Eng. Chem. Fundam. 15, 59–64 (1976).

    Article 
    CAS 

    Google Scholar
     

  • Nosé, S. A unified formulation of the constant temperature molecular dynamics methods. J. Chem. Phys. 81, 511–519 (1984).

    Article 
    ADS 

    Google Scholar
     

  • Essmann, U. et al. A smooth particle mesh Ewald method. J. Chem. Phys. 103, 8577–8593 (1995).

    Article 
    ADS 
    CAS 

    Google Scholar
     

  • Song, S. et al. Supplementary data for the paper “Scalable quasi-pure MOF membranes for energy-efficient gas separations”. Zenodo https://doi.org/10.5281/zenodo.20067808 (2026).



  • Source link

    Keep Up to Date with the Most Important News

    By pressing the Subscribe button, you confirm that you have read and are agreeing to our Privacy Policy and Terms of Use
    Add a comment Add a comment

    Leave a Reply

    Your email address will not be published. Required fields are marked *

    Previous Post
    Ketogenic diet mediates intestinal tumorigenesis through lipids not ketones

    Ketogenic diet mediates intestinal tumorigenesis through lipids not ketones

    Next Post
    An encyclopedia of human enhancer–gene regulatory interactions

    An encyclopedia of human enhancer–gene regulatory interactions

    Advertisement